Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclopentane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ2 N 1,N 11)rhenium(I)
نویسندگان
چکیده
In the title compound, [ReCl(C15H16N4)(CO)3], the Re(I) ion is coordinated in a distorted octa-hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo-pentane group is orientated in a transoid fashion with respect to the chloride ligand. The dihedral angle between the pryridine rings is 10.91 (12)°. In the crystal, N-H⋯Cl hydrogen bonds link complex mol-ecules, forming a two-dimensional network parallel to (001).
منابع مشابه
Tricarbonylchlorido(6′,7′-dihydro-5′H-spiro[cyclohexane-1,6′-dipyrido[3,2-d:2′,3′-f][1,3]diazepine]-κ2 N 1,N 11)rhenium(I)
In the title compound, [ReCl(C16H18N4)(CO)3], the Re(I) ion is coordinated in a distorted octa-hedral geometry by one Cl atom, two N atoms of the bidentate ligand and three carbonyl groups. The cyclo-hexane group is orientated in a transoid fashion with respect to the chloride ligand. In the crystal, N-H⋯Cl hydrogen bonds link complex mol-ecules, forming a two-dimensional network parallel to (1...
متن کامل5′-Amino-1,3-dioxo-2′,3′-dihydro-7′H-spiro[indane-2,7′-thieno[3,2-b]pyran]-6′-carbonitrile 1′,1′-dioxide
The title compound, C(16)H(10)N(2)O(5)S, was synthesized via the condesation of dihydro-thio-phen-3(2H)-one 1,1-dioxide, 1H-indene-1,2,3-trione and malononitrile in ethanol. The 2,3-dihydro-thio-phene 1,1-dioxide and pyran rings adopt envelope conformations. The mean planes through the planar part of the pyran ring and the benzene ring are nearly perpendicular, forming a dihedral angle of 88.40...
متن کاملcatena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ2 N 4,N 5)zinc(II)]-μ-pyrazine-2,3-dicarboxylato-κ3 N 1,O 2:O 3]
In the title compound, [Zn(C(6)H(2)N(2)O(4))(C(18)H(10)N(4))(H(2)O)](n) or [Zn(PZDC)(DPPZ)(H(2)O)](n) (where DPPZ is dipyrido[3,2-a:2',3'-c]phenazine and H(2)PZDC is pyrazine-2,3-dicarboxylic acid), the Zn atom is six-coordinated in a slightly distorted octa-hedral coordination geometry by three N atoms from one DPPZ ligand and one PZDC(2-) dianion, three O atoms from two different PZDC(2-) lig...
متن کاملcatena-Poly[[aqua(dipyrido[3,2-a:2′,3′-c]phenazine-κ2 N 4,N 5)iron(II)]-μ-pyrazine-2,3-dicarboxylato-κ3 N 1,O 2:O 3]
In the title compound, [Fe(C(6)H(2)N(2)O(4))(C(18)H(10)N(4))(H(2)O)](n), the Fe(II) ion adopts a slightly distorted octahedral mer-FeN(3)O(3) geometry, arising from one N,N'-bidentate dipyrido[3,2-a:2',3'-c]phenazine ligand, one N,O-chelating pyrazine-2,3-dicarboxyl-ate dianion and one water mol-ecule. An O-bonded symmetry-related dianion completes the coordination of the metal. The bridging di...
متن کاملAqua(3-carboxybenzoato-κO 1)(nitrato-κO)(dipyrido[3,2-a:2′,3′-c]phenazine-κ2 N 4,N 5)copper(II)
The title complex, [Cu(C(8)H(5)O(4))(NO(3))(C(18)H(10)N(4))(H(2)O)], was synthesized by reacting Cu(NO(3))(2), isophthalic acid and dipyridophenazine under hydro-thermal conditions. The Cu(II) ion is in a slightly distorted square-pyramidal coordination environment. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds connect complex mol-ecules into chains along [001].
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عنوان ژورنال:
دوره 69 شماره
صفحات -
تاریخ انتشار 2013